This work focused on the experimental determination of drying parameters during airflow drying licking countercurrent of Mangifera Indica L.
The samples were dried in a modular electric dryer operating in forced convection. The data collected made to draw the different drying kinetics of the mango at 40, 50 and 60°C. The solution of the Fick equation and the exploitation of the experimental data by the slope method have used. The values of the mass diffusivity coefficient vary between 1.83*10-7 and 2.25*10 -7 (m²/s), the activation energy Ea = 30.58 kJ/mol and the Arrhenius factor D0 = 9.74 x 10-5 m2/s.
Introduction
I. INTRODUCTION
Mass diffusivity is an important transport parameter for calculating the mass transfer within an agricultural product [1, 2]. When drying mango, [3] have shown that diffusion is the dominant physical mechanism of the drying process of this product. This coefficient largely determines the activity of surface water and partially conditions the quality of the finished product. Whether, it is a drying operation or hydration of foodstuffs, the knowledge of the mass diffusivity is necessary to be able to model the mass transfer process according to the operating conditions.
Thin layer drying kinetics of agricultural products generally exhibit a drying phase at a decreasing rate [4]. During this phase, it is no longer the external conditions of temperature and relative humidity of the drying air which manage the drying process, but it is the mode of water transfer from the breast of the product towards its surface, manages and controls this kinetics. This mode of transfer, which strongly depends on the type of product, its structure and especially its moisture, reflects the mechanisms driving the transport of moisture.
The mass diffusion coefficient is generally identified using drying kinetics, by analytical resolution or numerical resolution of the diffusion equation. The analytical method assumes a constant diffusion coefficient and moisture on surface that is instantly equal to its equilibrium value. In addition, the withdrawal of the product is not taken into account. Difficulties related to the modeling of the water transport phenomenon during a drying process led most researchers to limit themselves to a modeling represented by the diffusion equation (second law of Fick), introducing a coefficient mass diffusivity which includes the effects corresponding to all the phenomena that can cause the migration of water. The mass diffusivity coefficient is obtained by exploiting experimental results of the drying kinetics [5, 6].
Some studies show that the experimental methods most commonly used to determine the diffusivity coefficient are based on drying techniques [7, 8]. This diffusivity varies with the water content of the product and is determined from the slopes of the curves reflecting experimental drying kinetics. Several authors have used the slope method to determine the effective diffusivity coefficient: [9] on green beans, [10] on okro, [11, 12] on tomato, [13] on marjoram leaves, [14] on cocoa, [15] on the Iroko. Knowledge of the mass diffusion coefficient of biological materials makes it possible to estimate their drying times while giving possibilities of optimizing energy consumption during drying.
Thus, for the purpose of optimizing drying, works of [16] have shown that airflow drying licking countercurrent is also adjusted by one of the thin film drying models, encountered in the literature. The present work aims to complete this optimization of drying, by the experimental determination of the diffusion coefficient and the activation energy for this drying mode. It will be a question of showing the influence of the drying air temperature on the diffusion coefficient.
The curves of Figure 1 show the drying kinetics as a function of time at 40°C. These kinetics have the same pace, but the products on the trays do not reach their equilibrium moisture at the same time. The tray 1 reaches its equilibrium moisture faster than the tray 2, and so on. The curve (sum 40°C) represents the sum of the moisture ratio of all the trays. The peaks of the latter illustrate the entries of the different trays inside the drying chamber.
The curves of Figure 2 show that the drying rate profile increases at the beginning of drying and after a certain moisture value of each tray, it decreases only. It is found that the drying rate is higher in the first tray compared to the other screens up to a moisture ratio of 0.6. Below this last value, the difference between the curves becomes very small and tend to be similarly at the end of drying. On the other hand, it can also be seen that the drying rate decreases as a function of the moisture and as a function of the position of the screen relative to the heat source. Similar results were obtained by [19-21].
B. Effective Diffusivity
In figure 3, the effective diffusivities of mango were evaluated by determining the slopes of the curves of ln (MR) as a function of time for three different temperatures.
The effective diffusivity coefficient increases during the drying process as the temperature of the product increases. The values ??of the effective diffusivity coefficients vary between 1.83 x 10-7 and 2.25 x 10-7 m²/s. These results are consistent with those obtained by [22-24].
Figure 4 shows that the mass diffusivity coefficient decreases as the position of the product shelf increases. This leads us to say that it is not constant along the drying chamber.
Figure 4. Evolution of the effective diffusivity according to the position of the product in the dryer for different temperatures
It decreases as you move away from the heat source. It is even more important in the first tray than in the last tray. It tends to become constant towards the last position of the product tray in the drying chamber.
Each of the curves of the effective diffusivity coefficient during the drying of the mango made to obtain an equation in the form of a polynomial of second degree (equation 8) whose values ??of the coefficients are given in table 1.
Conclusion
In this work, the effective diffusivity during the airflow drying licking countercurrent of mango has been estimated experimentally. The curves of the diffusivity coefficient during this process have permitted to obtain an equation in the form of a second-degree polynomial. The Arrhenius equation yielded the value of the activation energy. The main results showed that the effective diffusion coefficient increases during the drying process with the increase of the temperature, on the other hand it decreases with the increase of the position of the product tray. Thus, the values of the effective diffusivity coefficient calculated for the three temperatures are in agreement with the literature and vary between 1.83 x 10-7 and 2.25 x 10-7 m2/s. The activation energy Ea = 30.58 kJ/mol.
A. Nomenclature
Deff : Effective moisture diffusivity (m2 /s),
M: One-time moisture
D0: Diffusivity coefficient at infinite temperatures (m2/s)
Me: Equilibrium moisture
Ea: Activation energy (kJ/mol)
M0: One-time water content
L: Half of the thickness of the slice (m) MR: Moisture Ratio
K: Drying constant n: Positive integer
t: Time x: Direction (m)
T: Drying air temperature (°C) R: gaze constant
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