Petroleum source rocks are those which has sufficient amount of organic matter to generate and expel hydrocarbons to form a commercial accumulation of oil or gas. The objective of this project is to analyze the principal learning on the application of the formation of petroleum source rocks and hydrocarbon generation to exploration activities along with evaluation of petroleum source rocks and hydrocarbon generation. In this project, samples of Barail Group and Disang Group of rocks of Naga-Schuppen Belt were analyzed to determine their source rock characteristics and petroleum generative potentials
Introduction
I. INTRODUCTION
To be a source rock, a rock must have three features:
Quantity of organic matter
Quality capable of yielding moveable hydrocarbons
Thermal maturity
The first two components are products of the depositional setting. The third is a function of the structural and tectonic history of the province.
Among the various techniques available, “van Krevelen” diagram and rock-eval pyrolysis are regularly being used in hydrocarbon exploration. They provide information on the kerogen type, sedimentary environment, effective source rock identification and its thermal maturity.
II. SAMPLES
The Disang Group and Barail Group of rocks occupies a vast region in Fold Belt of Assam-Arakan Basin. Data for source rock analysis are obtained from Disang Group and Barail group.
III. DATA ANALYSIS AND INTERPRETATION
Interpretation: Hydrogen Index (HI), mg HC/g TOC vs. Tmax? (Fig.1) is ploted from the data obtained from Barail and Disang group.
Hydrogen Index
The hydrogen index represents the amount of hydrogen relative to the amount of organic carbon present in a sample.
Tmax
We can use the general guidelines for maturation levels given below for Rock-Eval pyrolysis Tmax for types II and III kerogens. Different pyrolysis techniques have different cutoffs for pyrolysis oil and gas generation zone boundaries. Pyrolysis Tmax can be significantly different for type I kerogen or kerogen containing high sulfur concentration and is not a reliable indicator of maturity for these kerogen types. From the graph it can be interpreted that hydrocarbon generation zone of Barail group falls into type II and type III kerogen and most of the field of Disang group falls into oil and gas zone.
Interpretation: Fig.2 shows the Hydrogen Index (HI), mg HC/g TOC vs. Oxygen Index (OI),mg CO2/G TOC.
oxygen index (OI) : Oxygen index (OI) measured by Rock-Eval analysis provides reliable information about the early evolution stages of coals and type III kerogens.OI appeared to be a sensitive indicator during both simulated diagenesis and the entire oil window for gas-prone coal having a substantial humic contribution to its precursor material. The OI of oil-prone coal and coal with mixed oil and gas potential proved to be a valuable rank parameter only up to the beginning of the oil window. It could be utilized successfully for describing depth profiles in organic-rich intervals of early maturity in wells.
The oxygen index (OI) represents the amount of oxygen relative to the amount of organic carbon present in a sample.The HI vs. OI technique is used to determine source rock quality (kerogen type) of immature rocks. HI and OI change as a source rock matures (the amount of hydrogen and oxygen relative to carbon decreases and the HI/OI ratios converge toward the origin of the plot, leading one to a more gas-prone type III interpretation).
Interpretation: Production Index (PI) vs. Tmax? is shown in Fig.3. From the graph it can be seen that samples from Barail group enters into oil zone and samples from Disang group falls into oil zone and dry gas zone.
Interpretation: Fig 4 shows Hydrogen Index (HI), mg HC/g TOC vs. Total organic Carbon content (wt%). Both the samples from barail and disang groups falls unger gas prone zone where sample from barail group indicates good quality and Disang group indicates very good quality.
Interpretation: S1+S2 mg/gm rock vs. TOC Wt% is shown in fig.5. here, samples from barail group indicates poor quality and Disang group indicates fair quality.
Interpretation: Fig.6. shows S1 (mg/g) rock vs. TOC Wt%, where both the samples from barail and disang falls into Autochchthnous group. It refers to sediments that are native to its location.
Interpretation: S2 (mg/g) rock vs. TOC Wt% is shown in the fig.7. where most of the samples from Barail and Disang group falls into poor category.
Conclusion
The Rock Eval pyrolysis for samples from Barail Group and Disang Group of rocks of Naga Schuppen Belt have been analysed here. Various graphs are plotted which includes Hydrogen Index vs. Tmax, HI vs OI, Production index vs tmax, HI vs. TOC(wt%), S1+S2 vs TOC(wt%), S1 vs TOC(wt%), S2 vs TOC(wt%) and graphs are interpreted which indicates type of maturity, quality of hydrocarbon etc. Thermal maturity of organic matter in the analyzed samples is also evaluated based on the Tmax and production index “PI” value.
From the Fig 1, which indicates Hydrogen Index (HI), mg HC/g TOC vs. Tmax? of the barail and disang group, it can be interpreted that hydrocarbon generation zone of Barail group falls into type II and type III kerogen and most of the field of Disang group falls into oil and gas zone.
After plotting the data obtained from both of the groups,Fig 2 (Hydrogen Index vs. Oxygen Index) indicates to more gas-prone type III kerogen.
Production Index (PI) vs. Tmax? (Fig.3.) shows that samples from Barail group enters into oil zone and samples from Disang group falls into oil zone and dry gas zone.
Fig 4 (Hydrogen Index vs. Total organic Carbon content) indicates that barail group falls under good quality and Disang group falls under very good quality. And both the samples from barail and disang groups indicates gas prone zone.
S1+S2 vs. TOC ( Fig.5.) shows that samples from barail group is poor in quality and Disang group is fair in quality.
Fig.6. (S1 rock vs. TOC) where both the samples from barail and disang belongs to Autochchthnous group which means the sediments that are native to its location.
S2 rock vs. TOC which is shown in the fig.7, here most of the samples from Barail and Disang groups falls into poor category.
References
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